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Interaction of nitrobenzene by ArF-laser
Russian version
Puchikin A. V. 1, Panchenko Yu. N. 1,2, Andreev M. V. 2, Prokopiev V. E. 1,2
1Institute of High Current Electronics, Siberian Branch, Russian Academy of Sciences, Tomsk, Russia
2Tomsk State University, Tomsk, Russia
Email: apuchikin@mail.ru, yu.n.panchenko@mail.ru, andreevmv_86@mail.ru, prokop@ogl.hcei.tsc.ru
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A single-frequency process of interaction between the radiation of an excimer ArF laser and the vapor phase of nitrobenzene is considered. The fluorescence of vibrationally excited nitric oxide molecules formed during a photofragmentation of nitrobenzene is investigated. The influence of inert gases He, Ne and N2 on the fluorescence of the excited states of NO C2 and NO A2Σ, D2Σ has been demonstrated. In a nitrogen environment, the fluorescence of NO A2Σ (ν'=0) is enhanced due to the intermolecular non-radiative energy transfer from the metastable level N2 A3Σ to the electronic level of NO A2Σ. Keywords: nitro compound, photofragmentation, nitric oxide, fluorescence.
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