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Piezoelectric force microscopy for investigation the effect of electrical breakdown on the electrophysical properties of ferroelectric PVDF films
Buryanskaya E. L.
1,2, Polivets A. A.1, Kondrashov S.V.
1, Kiselev D.A.
2, Osipkov A. S.
1, Makeev M. O.
1
1Laboratory of ''Technologies of Polymer Ferroelectrics", Bauman Moscow State Technical University, Moscow, Russia
2Laboratory of Physics of Oxide Ferroelectrics, National University of Science and Technology MISIS, Moscow, Russia
2Laboratory of Physics of Oxide Ferroelectrics, National University of Science and Technology MISIS, Moscow, Russia
Email: buryanskayael@bmstu.ru
The effect of electrical breakdown on the electrophysical properties of PVDF films was investigated. The electrical strength of the material was determined before and after polarization. The piezoelectric coefficient d33 was measured using the quasi-static Berkelinecourt method. It was found that for unpolarized films after breakdown, the d33 values were nonzero, indicating local polarization in the pre-breakdown region. Using piezo response force microscopy (PFM), the morphology of the film surface was studied after electrical breakdown. Vertical and lateral piezoelectric response distribution signals were obtained. The values of local piezoelectric coefficients d33 were calculated in the vicinity and at a distance from the breakdown point. Keywords: ferroelectricity, piezoelectric force microscopy, polymer ferroelectrics, electrical breakdown, flexible electronics, smart materials.
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