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Study of the influence of uncontrolled impurities on the structural phase transition in GdFe3(BO3)4 using raman scattering
Russian version
Gudim I. A.1, Titova V. R.1, Moshkina E. M.1, Pavlovsky M. S.1, Krylov A. S.1, Eremin E. V.1
1Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia
Email: eev@iph.krasn.ru
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When obtaining single-crystal samples using the solution-melt method, the solvent can affect the composition of the grown crystals through the inclusion of uncontrolled impurities, which can significantly affect the properties of the compound. To study the effect of impurities on the structural phase transition in trigonal borate GdFe3(BO3)4, the temperature evolution of the Raman spectra of three single-crystal samples of this compound grown from three different solvents based on Bi2Mo3O12, K2MoO4 and Li2WO4 was investigated. It was shown that the structural transition temperature TS of Bi-substituted GdFe3(BO3)4 (TS=145 K) decreased relative to the impurity-free sample (TS=166 K). The inclusion of impurities from the solvent based on K2MoO4 does not affect the TS temperature, but affects the nature of the phase transition. The analysis of the obtained results was performed jointly with the calculation of the lattice dynamics. Keywords: rare earth ferroborates, structural phase transitions, Raman scattering, solution-melt method.
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