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Effect of the heterovalent cation substitution Bi3+->Ba2+ in BaTiO3 on the phase transition Pm-3m↔ P4mm and efficiency of energy harvesting
Russian version
Fokina V. D.1, Gorev M. V.1,2, Bondarev V. S.1,2, Molokeev M. S.1,2, Flerov I. N.1
1Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia
2Siberian Federal University, Institute of Engineering Physics and Radio Electronics, Krasnoyarsk, Russia
Email: fokina@iph.krasn.ru, gorev@iph.krasn.ru, vbondarev@yandex.ru, msmolokeev@mail.ru, flerov@iph.krasn.ru
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The heat capacity, thermal expansion and sensitivity to change of electric field of ceramic samples BaTiO3 and Ba0.97Bi0.02TiO3 were studied. The nature of the influence of chemical pressure and electric field on the main parameters of the phase transition Pm-3m↔ P4mm was revealed. The Olsen thermodynamic cycle was analyzed in the entropy-temperature diagram and the densities of the converted waste heat energy into electrical energy were determined. Keywords: phase transitions, ferroelectrics, heat capacity, thermal expansion, energy harvesting.
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