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Functionalization of MnFe2O4 magnetic nanoparticles for biomedical applications in magnetic fluid
Russian version
Kamzin A. S.1, Semenov V. G.2, Kamzina L. S.1
1Ioffe Institute, St. Petersburg, Russia
2St. Petersburg State University, St. Petersburg, Russia
Email: ASKam@mail.ioffe.ru
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The properties of magnetic nanoparticles (MNP) MnFe2O4 synthesized by the polyol method and then functionalized with 3-aminopropyltriethoxysilane (APTES) have been studied. The aim of the work is to create MNCs for magnetic fluid in biomedical applications, in particular for magnetic hyperthermic therapy of malignant tumors. The properties of the obtained particles were studied using X-ray diffraction and Mossbauer spectroscopy, which confirmed the single-phase nature of both MnFe2O4 MNP and functionalized MnFe2O_4@APTES composites. From the structural analysis, it was found that the average size of the synthesized particles is ~ 13 nm, which is consistent with the data of the Messbauro studies. Magnetic and Mossbauer studies have shown that both MnFe2O4 MNPCS and MnFe2O_4@APTES composites are superparamagnetic at room temperature. The functionalization (coating) of particles leads to a decrease in the effective magnetic field values compared to those observed in MnFe2O4 without coating, which is consistent with published data on a decrease in the magnetization of the MnFe2O_4@APTES composite. The decrease in magnetization and effective fields is explained by the fact that when MnFe2O4 MNP is functionalized, the APTES material covers the surface layer of particles and magnetic dipole interactions decrease. Keywords: polyol synthesis of MnFe2O4, nanoparticles, functionalization (coating) of APTES particles. The Mossbauer studies.
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