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Spectral properties of chiral carbon nanoparticles based on glutathione
Russian version
Stepanidenko E. A.1, Miruschenko M. D.1, Koroleva A.V.2, Zhizhin E.V.2, Mitroshin A. M.1,3, Parfenov P. S.1, Cherevkov S. A.1, Ushakova E. V.1
1International research and educational center for physics of nanostructures, ITMO University, Saint-Petersburg, Russia
2Research Park, Saint Petersburg State University, Saint Petersburg, Russia
3Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia
Email: eastepanidenko@itmo.ru, ofussr@itmo.ru, dalika@inbox.ru, evgeniy.zhizhin@spbu.ru, almitroshin51@gmail.com, qrspeter@gmail.com, s.cherevkov@itmo.ru, elena.ushakova@itmo.ru
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In this work, carbon nanoparticles (C-dots) were obtained from solution of chiral L-glutathione molecules in formamide. The resulting C-dots have photoluminescence (PL) in the red region of the spectrum at 370-470 nm and a high quantum yield for this band, reaching 10.8%. In the circular dichroism spectra of these C-dots, a signal in the optical transition region of 370-470 nm, associated with sp2-hybridized carbon domains doped with nitrogen and oxygen atoms was observed. Keywords: carbon dots, red photoluminescence, circular dichroism, chirality, glutathione.
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