Martyushov S. Yu.
1, Shul'pina I. L.
2, Lomov A. A.
3, Polyakov S. N.
11Technological Institute for Superhard and Novel Carbon Materials, Moscow, Russia
2Ioffe Institute, St. Petersburg, Russia
3Valiev Institute of Physics and Technology of RAS, Moscow, Russia
Email: mart@tisnum.ru
Structural defects of a diamond grown homoepitaxially by chemical vapor deposition (CVD) on a single-crystal substrate of a Ib diamond obtained by the high-pressure high-temperature method (HPHT) were studied using the methods of X-ray diffraction imaging (projection and section X-ray topography) and high-resolution (double-crystal) X-ray diffractometry. It is shown that there are no HPHT substrate defects in CVD diamond, but new ones are present - stacking faults of an unusual type and structure, which coexist with highly perfect crystal regions suitable for manufacturing elements of X-ray optics. For the first time, macrodefects were discovered, which were previously observed only in dislocation-free silicon single crystals. Keywords: HPHT diamond, synthetic diamond, structural defects, dislocations, stacking faults, X-ray diffraction imaging, section and projection topography, high-resolution X-ray diffractometry.
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