Physics of the Solid State
Volumes and Issues
Paramagnetic centers of vanadium and iron in Na5AlF2(PO4)2 single crystal
Vazhenin V. A. 1, Fokin A. V. 1, Potapov A. P. 1, Artyomov M. Yu. 1
1Institute of Natural Sciences and Mathematics, Ural Federal University, Yekaterinburg, Russia
Email: Vladimir.Vazhenin@urfu.ru, andrej.fokin@urfu.ru, Alexander.Potapov@urfu.ru, mikhail.artyomov@urfu.ru

PDF
The orientation behavior of the EPR-transitions of uncontrolled V4+ (S=1/2) and Fe3+ (S=5/2) impurity centers in a Na5AlF2(PO4)2 single crystal doped with chromium has been studied. The parameters of the spin Hamiltonian of these centers are determined both in the laboratory (crystallographic) and in the local coordinate systems. Based on the fact of the existence of mixed vanadate-phosphates and taking into account the orientation of the principal axis V4+, it was concluded that vanadium replaced the position of phosphorus. The closeness of the principal axes of the fine structure tensors of the second and fourth ranks of Fe3+ centers to the F-F direction of the fluorine-oxygen octahedron surrounding the iron ion was found. Keywords: impurity ions, paramagnetic resonance, hyperfine interaction.
  1. V.A. Vazhenin, A.P. Potapov, A.V. Fokin, M.Yu. Artemov. FTT 63, 11, 1915 (2021) (in Russian)
  2. J. Arlt, M. Jansen, H. Klassen, G. Schimmel, G. Heymer. Z. Anorg. Allg. Chem. 547, 179 (1987)
  3. D.M. Poojary, A. Clearfield, V.A. Timofeeva, S.E. Sigaryov. Solid State Ionics 73, 75 (1994)
  4. A.K. Ivanov-Shits, S.E. Sigariov, V.A. Timofeeva. FTT 32, 2, 624 (1990) (in Russian)
  5. A.K. Ivanov-Shits, S.E. Sigaryov. Solid State Ionics 40/41, 76 (1990)
  6. V.A. Timofeeva, Rost kristallov iz rastvorov-rasplavov Nauka, M., (1978). 267 p. (in Russian)
  7. John Lambe, Chihiro Kikuchi. Phys. Rev. 118, 1, 71 (1960)
  8. H.J. Gerritsen, H.R. Lewis. Phys. Rev. 119, 3, 1010 (1960)
  9. Chihiro Kikuchi, Inan Chen, William From, Paul B. Dorain. J. Chem. Phys. 42, 1, 181 (1965)
  10. I.N. Geifman, P.G. Nagorny, A.N. Usov, Fam za Ngy. FTT 33, 9, 2716 (1991) (in Russian)
  11. I.N. Geifman, P.G. Nagorny, M.V. Rotenfeld. FTT 36, 12, 3550 (1994) (in Russian)
  12. I.N. Geifman, I.S. Golovina, P.G. Nagorny. FTT 40, 3, 534 (1998) (in Russian)
  13. Dzh. Verts, J. Bolton. Teoriya i prakticheskie prilozheniya metoda EPR. Mir, M. (1975). 547 p. (in Russian)
  14. A. Abragam, B. Blini. Elektronnyj paramagnitnyj rezonans perekhodnykh ionov. Mir, M. (1973). 347 p. (in Russian)
  15. V.I. Pet'kov, M.V. Sukhanov, A.S. Shipilov, V.S. Kurazhkovskaya, E.Yu. Borovikova, N.V. Sakharov, M.M. Ermilova, N.V. Orekhova. Zhurn. neorgan. khimii 58, 1139, 2013 (2012) (in Russian)
  16. S.A. Altshuler, B.M. Kozyrev. Elektronnyi paramagnitnyi rezonans soedineniy elementov promezhutochnykh grupp. Nauka, M., (1972). P. 121. (in Russian)
  17. R.L. White, G.F. Herrmann, J.W. Carson, M. Mandel. Phys. Rev. 136, 1A, 231 (1964)
  18. N.M. Nizamutdinov, N.M. Khasanova, G.R. Bulka, V.M. Vinokurov, I.S. Rez, V.M. Garmash, N.I. Pavlova. Kristallografiya 32, 695, 1987 (1990) (in Russian)
  19. M.L. Meilman, M.I. Samoilovich. Vvedeniye v spektroskopiyu EPR aktivirovannykh monokristallov. Atomizdat, M. (1977). P. 109. (in Russian)

Подсчитывается количество просмотров абстрактов ("html" на диаграммах) и полных версий статей ("pdf"). Просмотры с одинаковых IP-адресов засчитываются, если происходят с интервалом не менее 2-х часов.

Дата начала обработки статистических данных - 27 января 2016 г.

Publisher:

Ioffe Institute

Institute Officers:

Director: Sergei V. Ivanov

Contact us:

26 Polytekhnicheskaya, Saint Petersburg 194021, Russian Federation
Fax: +7 (812) 297 1017
Phone: +7 (812) 297 2245
E-mail: post@mail.ioffe.ru