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White emission of polymeric luminescent compositions doped with boron chelates
Russian version
DOI: 10.21883/EOS.2022.08.54779.3382-22
Ishtokina E. Yu.1, Khrebtov A. A.1,2, Fedorenko E. V.2, Puzyrkov Z. N.1,2, Lim L. A.1, Mirochnik A. G.2
1Far Eastern Federal University, Vladivostok, Russia
2Institute of Chemistry, Far East Branch, Russian Academy of Sciences, Vladivostok, Russia
Email: ishtokina.eiu@students.dvfu.ru
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Multicomponent polymeric luminescent compositions doped with β-diketonates of boron difluoride were obtained, which can be used to produce white light by cascade radiative energy transfer. The white light is obtained by using the RGB model. The compositions containing four luminophores showed high color rendering values (color rendering index >80, 2776 K). Two luminescent transitions were realized in the obtained compositions for the red dye (R): S1-> S0, associated with cascade radiative energy transfer along the chain of luminophores, and S2-> S1->S0, directly excited by UV radiation. The luminous characteristics of the obtained compositions indicate the possibility of using polymeric luminescent compositions doped with β-diketonate boron difluoride in emergency and indoor lighting devices. Keywords: β-diketonates of boron difluoride, luminescence, polymer compositions, energy transfer, white light, illumination.
  1. GOST R 55702-2020. Electric light sources. Methods of measuring electrical and light parameters [Electronic resource]. URL: https://docs.cntd.ru/document/1200177515
  2. S. Kitsinelis, G. Zissis, L. Arexis. Light and Engineering, 20 (3), 25 (2012)
  3. Yu. Davidenko. Modern Electronics, 10, 36 (2005)
  4. O.R. Abdullaev, A.V. Aluev, Yu.L. Akhmerov, N.V. Kourova, M.V. Mezhennyi, A.A. Chelny. Quantum Electron., 47 (10), 927 (2017). DOI: 10.1070/QEL16396
  5. SP 52.13330.2016. Natural and artificial lighting [Electronic resource]. URL: https://docs.cntd.ru/document/456054197
  6. Decree 2255 of the Government of the Russian Federation dated December 24, 2020 On approval of requirements for lighting devices and electric lamps used in AC circuits for lighting purposes [Electronic resource]. URL: https://docs.cntd.ru/document/573230500
  7. V.N. Deinego, V.A. Kaptsov. Hygiene and Sanitation, 92 (6), 81 (2013)
  8. G. Zeng, Q. Dong, W. Bao. J. Appl. Spectrosc., 83 (3), 460 (2016). DOI: 10.1007/s10812-016-0311-4
  9. N.M. Khaidukov, M.N. Brekhovskikh, N.Y. Kirikova, V.A. Kondratyuk, V.N. Makhov. Rus. J. Inorg. Chem., 65 (8), 1135 (2020). DOI: 10.1134/S0036023620080069
  10. S. Mukherjee, P. Thilagar. Dyes Pigm., 110, 2 (2014). DOI: 10.1016/j.dyepig.2014.05.031
  11. I.R. Mardaleishvili, G.V. Lyubimova, L.S. Kol'tsova, A.I. Shienok, P.P. Levin, A.S. Tatikolov, N.L. Zaichenko. High Energy Chem., 52 (3), 240 (2018). DOI: 10.1134/S0018143918030098
  12. A. G. Mirochnik, E. V. Fedorenko, D. Kh. Shlyk. Russ. Chem. Bull., 65 (3), 806 (2016). DOI: 10.1007/s11172-016-1378-z
  13. N. Gelfand, A. Freidzon, E. Fedorenko. J. Mol. Struct., 1151, 177 (2018). DOI: 10.1016/j.molstruc.2017.09.045
  14. A. Sakai, M. Tanaka, E. Ohta , Y. Yoshimoto, K. Mizuno, H. Ikeda. Tetrahedron Lett., 53, 4138 (2012). DOI: 10.1016/j.tetlet.2012.05.122
  15. E.V. Fedorenko, A.A. Khrebtov, A.G. Mirochnik, P.S. Nefedov, L.A. Lim, V.A. Reutov, I.S. Pavlov, A.A. Sergeev. Opt. Spectrosc., 127 (3), 459 (2019). DOI: 10.1134/S0030400X19090091
  16. A.A. Khrebtov, E.V. Fedorenko, L.A. Lim, V.A. Reutov. Opt. Spectrosc., 124 (1), 71 (2018). DOI: 10.1134/S0030400X18010095
  17. E.V. Gukhman, V.A. Reutov, Russ. J. Gen. Chem., 69 (10), 1608 (1999)
  18. S.A. Tikhonov, V.I. Vovna, I.S. Osmushko, E.V. Fedorenko, A.G. Mirochnik. Spectrochim. Acta A, 189, 563 (2018). DOI: 10.1016/j.saa.2017.08.059
  19. G. Bai, C. Yu, C. Cheng, E. Hao, Y. Wei, X. Mu, L. Jiao. Org. Biomol. Chem., 12 (10), 1618 (2014). DOI: 10.1039/C3OB42201A
  20. E.V. Fedorenko, A.G. Mirochnik, A.Yu. Beloliptsev, V.V. Isakov. Dyes Pigm., 109, 181 (2014). DOI: 10.1016/j.dyepig.2014.04.016
  21. A.G. Mirochnik, B.V. Bukvetskii, E.V. Fedorenko, V.E. Karasev. Russ. Chem. Bull., 53 (2), 291 (2004)
  22. E.V. Fedorenko, A.A. Khrebtov, A.G. Mirochnik, E.Yu. Ishtokina, V.A. Reutov, L.A. Lim. J. Lumin., 235, 118043 (2021). DOI: 10.1016/j.jlumin.2021.118043

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