Spectral study of the structure and properties of complexes of unsubstituted indoline spiropyran with aluminum ions
Belikov N. E.1, Lukin A. Yu. 2, Varfolomeev S. D. 1, Levina I. I. 1, Petrovskaya L. E. 3, Demina O. V. 1, Barachevsky V. A. 4, Khodonov A. A. 1
1Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia
2MIREA - Russian Technological University, Moscow, Russia
3Shemyakin–Ovchinnikov Institute of Bioorganic Chemistry of the Russian Academy of Sciences, Moscow, Russia
4Photochemistry Center, FSRC "Crystallography and Photonics", Russian Academy of Sciences, Moscow, Russia

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The methods of absorption electronic and NMR spectroscopy were used to study the processes of complexation during the interaction of molecules of unsubstituted indoline spiropyran with aluminum salts. The mechanism of formation and structure of complexes of two types has been established. Negative photochromism of the complex of the merocyanine form of spiropyran with aluminum ions was found. The stability of metal complexes to the action of various agents has been investigated. Keywords: photochromism, spiropyrans, metal complexes, aluminum salts, electron spectroscopy, NMR spectroscopy.
  1. Organic Photochromic and Thermochromic Compounds ed. by J.C. Crano, R.J. Gugliemetti, (Plenum Press, N.Y., London, 1999), vol. 1-2
  2. Photochromic Materials, ed. by H. Tian, J. Zhang (Wiley-VCH Verlag, Weinheim, 2016)
  3. A.A. Ali, R. Kharbash, Y. Kim. Analytica Chimica Acta, 1110, 199 (2020). DOI: 10.1016/j.aca.2020.01.057
  4. L. Kortekaas, W.R. Browne. Chem. Soc. Rev., 48 (12), 3406 (2019). DOI: 10.1039/c9cs00203k
  5. P.R. Sahoo, K. Prakash, S. Kumar. Coordination Chemistry Rev., 357 (1), 18 (2018). DOI: 10.1016/j.ccr.2017.11.010
  6. C. Coudret, A.V. Chernyshev, A.V. Metelitsa, J.C. Micheau. In: Photon-Working Switches, ed. by Y. Yokoyama, K. Nakatani (Springer, Japan, 2017), ch. 1, p. 3-36. DOI: 10.1007/978-4-431-56544-4
  7. K.V. Zvezdin, N.E. Belikov, A.V. Laptev, A.Yu. Lukin, O.V. Demina, P.P. Levin, S.B. Brichkin, M.G. Spirin, V.F. Razumov, V.I. Shvets, A.A. Khodonov. Rossiyskiye nanotekhnologii, 7 (5-6), 112 (2012) (in Russian). DOI: 10.1134/S1995078012030172
  8. V.A. Barachevsky. Review J. Chem., 3 (1), 52 (2013). DOI: 10.1134/S2079978012040012
  9. J. Ren, H. Tian. Sensors, 7 (12), 3166 (2007). DOI: 10.3390/s7123166
  10. T.J. Feuerstein, R. Muller, C. Barner-Kowollik, P.W. Roesky. Inorg. Chem., 58 (22), 15479 (2019). DOI: 10.1021/acs.inorgchem.9b02547
  11. V.K. Seiler, K. Robeyns, N. Tumanov, D. Cincic, J. Wouters, B. Champagne, T. Leyssens. CrystEngComm, 21, 4925 (2019). DOI: 10.1039/c9ce00805e
  12. E.I. Balmond, B.K. Tautges, A.L. Faulkner, V.W. Or, B.M. Hodur, J.T. Shaw, A.Y. Louie. J. Org. Chem., 81 (19), 8744 (2016). DOI: 10.1021/acs.joc.6b01193
  13. P.P. Levin, N.E. Belikov, I.I. Levina, A.S. Tatikolov, A.A. Khodonov, I.V. Khudyakov. J. Phys. Org. Chem., 32, e4012 (2019). DOI: 10.1002/poc.4012
  14. L. Kortekaas, J. Chen, D. Jacquemin, W.R. Browne. J. Phys. Chem. B., 122 (24), 6423 (2018). DOI: 10.1021/acs.jpcb.8b03528
  15. V.A. Murin, V.F. Mandzhikov, V.A. Barachevsky. Opt. i spektr., 40, 1084 (1976) (in Russian)
  16. V.A. Murin, V.F. Mandzhikov, V.A. Barachevsky. Opt. i spektr., 42 (1), 89 (1977) (in Russian)
  17. A.K. Chibisov, H. Gorner. Phys. Chem. Chem. Phys., 3 (3), 424 (2001). DOI: 10.1039/b007713p
  18. H. Gorner. Phys. Chem. Chem. Phys., 3 (3), 416 (2001). DOI: 10.1039/b007708i
  19. S. Toppet, W. Quintens, G. Smets. Tetrahedron, 31 (16), 1957 (1975). DOI: 10.1016/0040-4020(75)87058-X
  20. J. Hobley, V. Malatesta, R. Millini, L. Montanari, W.O. Parker. Phys. Chem. Chem. Phys., 1 (14) 3259 (1999). DOI: 10.1039/A902379H
  21. J. Hobley, V. Malatesta. Phys. Chem. Chem. Phys., 2 (1), 57 (2000). DOI: 10.1039/A908360J
  22. C.L. Fleming, S. Li, M. Grotli, J. Andreasson. J. Am. Chem. Soc., 140 (43), 14069 (2018). DOI: 10.1021/jacs.8b09523
  23. S.-R. Keum, K.-B. Lee, P.M. Kazmaier, R.A. Manderville, E. Buncel. Magnetic Resonance in Chemistry, 30 (11), 1128 (1992). DOI: 10.1002/mrc.1260301119
  24. P.P. Levin, A.S. Tatikolov, A.V. Laptev, A.Y. Lukin, N.E. Belikov, O.V. Demina, A.A. Khodonov, V.I. Shvets, S.D. Varfolomeev. J. Photochem Photobiol. A, 231, 41 (2012). DOI: 10.1016/j.jphotochem.2011.12.024

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