Physics of the Solid State
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Investigation of Polyvinyl Alcohol-CuS Compound with Metal-Like Conductivity
Prosanov I. Yu.1, Romanenko A. I.
2, Chebanova G. E.
2
1Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Email: prosanov@mail.ru, air@niic.nsc.ru, yakovleva@niic.nsc.ru
PVA-CuS compound produced from hybrid interpolymeric polyvinyl alcohol (PVA)-CuCl2 complex through solid state sulfurization was investigated by means of X-ray diffraction, UV-Vis and Raman spectroscopy, and direct current measurements. It is claimed that CuS in this compound has one-dimensional structure. This result is achieved by using a precursor technique based on diffusion limitation at solid state synthesis, so that the structure of initial reagents is inherited by reaction products. The produced material is determined to possess metal-type conductivity and thermopower in the vicinity of room temperature. Keywords: hybrid interpolymeric complexes, polyvinyl alcohol, CuS, inorganic polymers, one-dimensional structures, electrical properties.
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