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Luminescent properties of solid solutions of yttrium-scandium phosphates doped with europium ions
Russian version
DOI: 10.21883/PSS.2022.12.54383.449
Wozniak-Levushkina V. S.1, Arapova A. A.1, Spassky D. A.2,3, Nikiforov I. V.4, Zadneprovsky B. I.5
1Moscow State University, Moscow, Russia
2Lomonosov Moscow State University, Skobeltsyn Institute of Nuclear Physics, Moscow, Russia
3Institute of Physics, University of Tartu, Tartu, Estonia
4Department of Chemistry, Lomonosov Moscow State University, Moscow, Russia
5All-Russian Research Institute for the Synthesis of Mineral Raw Materials, Alexandrov, Russia
Email: levushkina@physics.msu.ru
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The luminescent properties of solid solutions Y1-xScxPO4 : 0.5 mol.% Eu3+ (x=0,0.2, 0.4, 0.5, 0.6, 0.8, 1) under excitation by ultraviolet and vacuum-ultraviolet radiation were studied. The influence of disorder of the crystal structure in solid solutions on the structure of Eu3+ luminescence spectra is shown. A non-linear dependence of values of the optical band gap on solid solution composition was obtained and a model was suggested to explain this effect. Keywords: energy transfer, luminescence, solid solutions, ScPO4 : Eu3+, YPO4 : Eu3+.
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