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Chemical pressure, structural instability, and IR-active phonons in a series of rare-earth analogues of francisite Cu3RE(SeO3)2O2Cl
Russian version
DOI: 10.21883/EOS.2022.01.52986.22-21
Novikova N. N.1, Yakovlev V. A.1, Kuznetsova E. S.2, Berdonosov P.S. 2, Klimin S. A.1
1Institute of Spectroscopy, Russian Academy of Sciences, Troitsk, Moscow, Russia
2Department of Chemistry, Lomonosov Moscow State University, Moscow, Russia
Email: novik@isan.troitsk.ru, yakovlev@isan.troitsk.ru, berdonosov@inorg.chem.msu.ru
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ATR and transmission spectra of a series of rare-earth francisite-like phases Cu3RE(SeO3)2O2Cl (RE is a rare earth element, RE = Nd, Sm, Eu, Gd, Dy, Ho, Tm, Yb) were studied. The frequencies of the IR-active phonons of the crystals under study were determined. In the dependences of phonon frequencies on the ionic radius in a series of isostructural compounds, two tendencies are observed: a hardening of frequencies due to an increase in chemical pressure and a softening of the vibration frequencies, in which rare-earth ions are involved, due to an increase in the mass of a specific rare-earth ion. In the Cu3Dy(SeO3)2O2Cl crystal, an anomalous softening of low-frequency phonons at low temperatures was observed, which was apparently associated with the structural instability of the compound. Keywords: rare-earth francisite-like phases, optical spectroscopy, IR-active phonons, chemical pressure.
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