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Spectral characteristics and energy transfer Ce³⁺->Tb³⁺->Eu³⁺ in LuBO₃(Ce, Tb, Eu) compound

Russian version

DOI: 10.21883/PSS.2022.01.52496.217

Shmurak S. Z.

¹, Kedrov V. V.

¹, Kiselev A. P.

¹, Fursova T. N.

¹, Zver'kova I. I.

¹Osipyan Institute of Solid State Physics RAS, Chernogolovka, Russia

Email: shmurak@issp.ac.ru

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The structure, IR, luminescence, and luminescence excitation spectra of Ce³⁺, Tb³⁺, and Eu³⁺ ions in Lu_1-2xCe_xEu_xBO₃ and Lu_0.91-2xCe_xTb_0.09Eu_xBO₃ solid solutions were studied. The minimum "threshold" distance between Ce³⁺ and Eu³⁺ ions was estimated, at which there is no charge transfer between these ions, leading to the quenching of Ce³⁺ and Eu³⁺ luminescence. It is shown that in Lu_0.91-2xCe_xTb_0.09Eu_xBO₃ compounds, the range of Ce and Eu concentrations of 0.2-0.25 at.% is optimal for obtaining the maximum luminous intensity of this compound. Keywords: phosphors for LEDs, rare earth orthoborates, X-ray diffraction analysis, IR spectroscopy, luminescence spectra.

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