Physics of the Solid State
Volumes and Issues
Phase composition, structure and transport characteristics of ZrO2-Sc2O3 solid solution crystals additionally doped with Yb2O3
Borik M. A.1, Korableva G. M.1,2, Kulebyakin A. V.1, Kuritsyna I. E.1,2, Lomonova E. E.1, Milovich F. O.1,3, Myzina V. A.1, Tabachkova N. Yu.1,3
1Prokhorov General Physics Institute of the Russian Academy of Sciences, Moscow, Russia
2Osipyan Institute of Solid State Physics RAS, Chernogolovka, Russia
3National University of Science and Technology MISiS, Moscow, Russia
Email: kulebyakin@lst.gpi.ru

PDF
The effect of the co-doped Yb2O3 on the transport characteristics and stabilization of the cubic phase in solid solutions based on ZrO2-Sc2O3 has been carried out. (ZrO2)1-x-y(Sc2O3)x(Yb2O3)y solid solution crystals, where (x=0.07-0.09; y=0.01-0.03), were grown by directional crystallization of the melt in a cold crucible. It is shown that crystals with a cubic fluorite structure were obtained at a total concentration of stabilizing oxides Sc2O3 and Yb2O3 above 10 mol%. At a fixed concentration of Sc2O3, crystals with a total concentration of stabilizing oxides of 10 mol.%, which have the structure of a pseudocubic t''-phase, have the maximum conductivity. Crystals with a total concentration of stabilizing oxides of 10 mol, having a pseudocubic t''-phase structure, at a fixed concentration of Sc2O3, have the maximum conductivity. It is shown that an increase in the Yb2O3 concentration in the field of cubic solid solutions leads to a decrease in the conductivity of the crystals. The (ZrO2)0.9(Sc2O3)0.09(Yb2O3)0.01 crystals have the maximum conductivity in the entire temperature range. Keywords: Crystal growth from melt, zirconium dioxide, solid electrolytes.
  1. S.P.S. Badwal, F.T. Ciacchi, D. Milosevic. Solid State Ionics 136-137, 91 (2000)
  2. J.W. Fergus. J. Power Sources 162, 30 (2006)
  3. J. Fergus. J. Minerals, Met. Mater. Soc. 59, 56 (2007)
  4. S.C. Singhal, K. Kendall. High Temperature Solid Oxide Fuel Cells: Fundamentals, Design, and Applications. Elsevier Science Ltd., Oxford (2003). P. 387-389
  5. V.V. Kharton, F.M.B. Marques, A. Atkinson. Solid State Ionics 174, 135 (2004)
  6. M. Morales, M. Segarra. Materials Issues for Solid Oxide Fuel Cells Design. Handbook of Clean Energy Systems. John Wiley \& Sons, Ltd. (2015). P. 1-15
  7. R. Ruh, H.J. Garrett, R.F. Domagala, V.A. Patel. J. Am. Ceram. Soc. 60, 9, 400 (1977)
  8. M. Yashima, M. Kakihana, M. Yoshimura. Solid State Ionics 86-88, 1131 (1996)
  9. T.-S. Sheu, J. Xu, T.-Y. Tien. J. Am. Ceram. Soc. 76, 8, 2027 (1993)
  10. H. Fujimori, M. Yashima, M. Kakihana, M. Yoshimura. J. Am. Ceram. Soc. 81, 2885 (1998)
  11. H. Fujimori, M. Yashima, M. Kakihana, M. Yoshimura. J. Appl. Phys. 91, 6493 (2002)
  12. W. Araki, T. Koshikawa, A. Yamaji, T. Adachi. Solid State Ionics 180, 1484 (2009).
  13. O. Yamamoto, Y. Arai, Y. Takeda, N. Imanishi, Y. Mizutani, M. Kawai, Y. Nakamura. Solid State Ionics 79, 137 (1995)
  14. K. Nomura, Y. Mizutani, M. Kawai, Y. Nakamura, O. Yamamoto. Solid State Ionics 132, 235 (2000)
  15. K. Du, C.-H. Kim, A.H. Heuer, R. Goettler, Z. Liu. J. Am. Ceram. Soc. 91, 1626 (2008)
  16. D.A. Agarkov, M.A. Borik, S.I. Bredikhin, I.N. Burmistrov, G.M. Eliseeva, V.A. Kolotygin, A.V. Kulebyakin, I.E. Kuritsyna, E.E. Lomonova, F.O. Milovich, V.A. Myzina, P.A. Ryabochkina, N.Yu. Tabachkova, T.V. Volkova. J. Materiomics 5, 273 (2019)
  17. H.A. Abbas, C. Argirusis, M. Kilo, H.-D. Wiemhofer, F.F. Hammad, Z.M. Hanafi. Solid State Ionics 184, 1, 6 (2011)
  18. S. Omar, W.B. Najib, W. Chen, N. Bonanos. J. Am. Ceram. Soc. 95, 1965 (2012)
  19. M.A. Borik, S.I. Bredikhin, V.T. Bublik, A.V. Kulebyakin, I.E. Kuritsyna, E.E. Lomonova, F.O. Milovich, V.A. Myzina, V.V. Osiko, P.A. Ryabochkina, S.V. Seryakov, N.Yu. Tabachkova. J. Cryst. Growth 457, 122 (2017)
  20. V.V. Lakshmi, R. Bauri. Solid State Sci. 13, 1520 (2011)
  21. V. Shukla, A. Kumar, I.L. Basheer, K. Balani, A. Subramaniam, S. Omar. J. Am. Ceram. Soc. 100, 204 (2017)
  22. A. Yamaji, T. Koshikawa, W. Araki, T. Adachi. J. Eng. Mater. Technol. 131, 011010 (2008)
  23. A. Spirin, V. Ivanov, A. Nikonov, A. Lipilin, S. Paranin, V. Khrustov, A. Spirina. Solid State Ionics 225, 448 (2012)
  24. A. Kumar, A. Jaiswal, M. Sanbui, S. Omar. J. Am. Ceram. Soc. 100, 2, 659 (2017)
  25. S. Terauchi, H. Takizawa, T. Endo, S. Uchida, T. Terui, M. Shimada. Mater. Lett. 23, 273 (1995)
  26. D.-S. Lee, W. Kim, S. Choi, J. Kim, H.-W. Lee, J.-H. Lee. Solid State Ionics 176, 33 (2005)
  27. Z. Wang, M. Cheng, Z. Bi, Y. Dong, H. Zhang, J. Zhang, Z. Feng, C. Li. Mater. Lett. 59, 2579 (2005)
  28. S.T. Norberg, S. Hull, I. Ahmed, S.G. Eriksson, D. Marrocchelli, P.A. Madden, P. Li, J.T.S. Irvine. Chem. Mater. 23, 6, 1356 (2011)
  29. J.T.S. Irvine, J.W.L. Dobson, T. Politova, S.G. Martin, A. Shenouda. Faraday Discussions 134, 41 (2006)
  30. V.V. Osiko, M.A. Borik, E.E. Lomonova, Synthesis of refractory materials by skull melting. In: Springer hand book of crystal growth. Springer, N. Y. (2010). P. 433-477
  31. X.J. Chen, K.A. Khor, S.H. Chan, L.G. Yu. Mater. Sci. Eng. A 335, 1-2, 246 (2002)
  32. M. Hirano, S. Watanabe, E. Kato. J. Am. Ceram. Soc. 82, 10, 2861 (1999)
  33. A. Cheikh, A. Madani, A. Touati, H. Boussetta, C. Monty. J. Eur. Ceram. Soc. 21, 1837 (2001)
  34. M. Aoki, Y.-M. Chiang, I. Kosacki, L.J.-R. Lee, H. Tuller, Y. Liu. J. Am. Ceram. Soc. 79, 1169 (1996)
  35. S. Shukla, S. Seal, R. Vij, S. Bandyopadhyay. NanoLetters 3, 3, 397 (2003)
  36. P. Mondal, A. Klein, W. Jaegermann, H. Hahn. Solid State Ionics 118, 331 (1999)
  37. S. Berendts, M. Lerch. J. Cryst. Growth. 371, 28 (2013)
  38. I. Valov, V. Ruhrup, R. Klein, T.-C. Rodel, A. Stork, S. Berendts, M. Dogan, H.-D. Wiemhofer, M. Lerch, J. Janek. Solid State Ionics. 180, 1463 (2009).
  39. J.-P. Eufinger, M. Daniels, K. Schmale, S. Berendts, G. Ulbrich, M. Lerch, H.-D. Wiemhofer, J. Janek. Phys. Chem. Chem. Phys. 46, 25583 (2014)
  40. M.A. Borik, S.I. Bredikhin, V.T. Bublik, A.V. Kulebyakin, I.E. Kuritsyna, E.E. Lomonova, F.O. Milovich, V.A. Myzina, V.V. Osiko, P.A. Ryabochkina, N.Yu. Tabachkova. J. Am. Ceram. Soc. 100, 12, 5536 (2017)
  41. M. Borik, G. Korableva, A. Kulebyakin, I. Kuritsyna, N. Larina, E. Lomonova, F. Milovich, V. Myzina, P. Ryabochkina, N. Sidorova, N. Tabachkova, T. Volkova. Crystals 11, 2, 83 (2021)
  42. H. Fujimori, M. Yashima, M. Kakihana, M. Yoshimura. J. Am. Ceram. Soc. 81, 11, 2885 (1998)
  43. Y. Hemberger, N. Wichtner, C. Berthold, K.G. Nickel. Int. J. Appl. Ceram. Technol. 13, 1, 116 (2016).

Подсчитывается количество просмотров абстрактов ("html" на диаграммах) и полных версий статей ("pdf"). Просмотры с одинаковых IP-адресов засчитываются, если происходят с интервалом не менее 2-х часов.

Дата начала обработки статистических данных - 27 января 2016 г.

Publisher:

Ioffe Institute

Institute Officers:

Director: Sergei V. Ivanov

Contact us:

26 Polytekhnicheskaya, Saint Petersburg 194021, Russian Federation
Fax: +7 (812) 297 1017
Phone: +7 (812) 297 2245
E-mail: post@mail.ioffe.ru