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The Effect of Heat Treatment on the Thermal Conductivity of Single Crystals of Solid Solutions Based on ZrO2 Stabilized by Scandium, Cerium, and Yttrium Oxides
Russian version
Agarkov D. A.1, Borik M. A.2, Vakulina E.V.3, Ezhikova E. V.2, Kulebyakin A. V.2, Lomonova E. E. 2, Milovich F. O.4, Myzina V. A.2, Popov P. A.3, Reu A. A.2, Ryabochkina P. A.5, Tabachkova N. Yu.2,4, Chislov A. S.2,4
1Osipyan Institute of Solid State Physics RAS, Chernogolovka, Russia
2Prokhorov General Physics Institute of the Russian Academy of Sciences, Moscow, Russia
3Petrovsky Bryansk State University, Bryansk, Russia
4National University of Science and Technology MISiS, Moscow, Russia
5Ogarev Mordovian State University, Saransk, Russia
Email: chislov.as@misis.ru
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The effect of heat treatment at 1000 oC for 400 h on thermal conductivity of zirconium dioxide crystals co-doped with scandium and cerium oxides, as well as additionally doped with yttrium oxide, has been studied. It was demonstrated that crystal annealing, depending on composition, resulted in phase and structural changes associated with the ordering of oxygen vacancies, which impacted the thermal conductivity in the temperature range 50-300 K. The introduction of Y2O3 into the composition of stabilizing additives increased the phase and structural stability of crystals. With the rise of total concentration of doping impurities the effect of annealing on thermal conductivity was noticed to decline. Keywords: zirconium dioxide, structure, annealing, physicochemical properties.
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