Dilatometric studies of the reverse piezoelectric effect in solid solutions (1-x)Na1/2Bi1/2TiO3-xBaTiO3
Gorev M.V.1,2, Sapozhnikov S.V.2, Flerov I.N.1
1Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia
2Siberian Federal University, Institute of Engineering Physics and Radio Electronics, Krasnoyarsk, Russia
Email: gorev@iph.krasn.ru
Studies of the effect of a low-intensity electric field (E<10 kV/cm) on the formation of the inverse piezoelectric effect in ceramic solid solutions (1-x)Na1/2Bi1/2TiO3-xBaTiO3 (x=0.05-0.97). In the region of phase transition Pm3m↔ P4mm, ceramics with a high concentration of barium titanate are characterized by a large, close to saturation value of the normalized piezoelectric coefficient d33* (x=0.95, d33*~750 pm/V, E=3.3 kV/cm). In solid solutions close in composition to the morphotropic phase boundary (MPB), the derivative d(d33*)/dE increases with increasing field strength. A correlation has been established between the degree of tetragonality of the crystal lattice and the behavior/values of field-induced deformation, deformation hysteresis, piezoelectric coefficient, thermal expansion, and polarization. Keywords: phase transitions, lead-free ferroelectrics, piezoelectric effect.
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