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Synthesis, characterizations and magnetic properties of new (MnS)1-x(TiN)x compounds
Russian version
Abramova G .M.1, Syrokvashin M. M.2,3, Skorobogatov S. A1, Velikanov D. A1, Vorotynov A. M.1, Filatova I. Yu.2, Sulyaeva V. S.2
1Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia
2Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
3Siberian State University of Railway Engineering, Novosibirsk, Russia
Email: agm@iph.krasn.ru, sasa@iph.krasn.ru
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The (MnS)1-x(TiN)x solid solutions have first been synthesized by cation-anion substitution on the basis of the isostructural heterovalent α-Mn2+S2 (antiferromagnetic semiconductor) and Ti3+N3- (low-temperature superconductor) compounds with a NaCl-type cubic structure. It has been established that anions (S and N) in the (MnS)1-x(TiN)x (x<0.10) solid solutions generally retain their valence, while the substitution cation (Ti) can be in different valence states. Cation-anion substitution changes the valence band of the α-MnS matrix via the occurrence of the contribution of titanium d electrons in the vicinity of the Fermi level and reduces the magnetic susceptibility in the paramagnetic state without a significant change in the α-MnS Neel temperature; accordingly, the spin-flop transition in the low-temperature region becomes less pronounced. Keywords: magnetically ordered materials, crystal growth, cation-anion substitution.
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