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Resistive gas sensors based on a polyene-polyyne structure with embedded TiO2 nanoparticles
Russian version
Nuriahmetov I. F.1, Streletskiy O. A. 1, Pavlikov A. V. 1, Savchenko N. F. 1, Tatarintsev A. A. 1, Khaidarov A. A. 1
1Lomonosov Moscow State University, Moscow, Russia
Email: islam.nuriakhmetov@mail.ru
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The paper presents the results of studies of gas sensors based on a polyene-polyyne structure with embedded TiO2 nanoparticles. The samples were prepared by dissolving polyvinylidene fluoride in N,N-dimethylformamide followed by its dehydrohalogenation at different concentrations of TiO2 nanoparticles. The structure of the samples was studied using scanning electron microscopy, energy-dispersive X-ray spectroscopy, Raman spectroscopy, and infrared Fourier transform spectroscopy. The research results show that the obtained samples are porous films based on polyene-polyyne chains, in the matrix of which TiO2 nanoparticles are located. Studies of the sensory properties of the manufactured samples were carried out for various concentrations of ethanol, acetone, and ammonium hydroxide vapors. The samples showed a general increase in sensitivity to all the gases studied with an increase in the concentration of TiO2 nanoparticles. With an increase in the mass fraction of TiO2 nanoparticles, an optimal value was observed, at which the sensitivity to ammonium hydroxide vapors became maximum. Keywords: Polyene-polyyne chains, dehydrohalogenation, TiO2 nanoparticles, composites, selective resistive sensing, porous sp-based films.
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