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Study of the structure of powdered nanocelluloses isolated from industrial waste using X-ray diffraction and computer modeling methods
Russian version
Prusskii A.I. 1, Tokko O.V. 1, Kadetova A. B. 1, Kotelnikova N.Ею2, Kiselev V.V. 1
1Petrozavodsk State University, Petrozavodsk, Russia
2Branch of Petersburg nuclear physics institute named by B.P.Konstantinov of National research centre «Kurchatov institute» – Institute of macromolecular compounds, Gatchina, Leningrad Region, Russia
Email: prusskiiandrey@gmail.com, solvak@yandex.ru, ttyc9@mail.ru, xatab3451@gmail.com
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Structural studies of powder samples of nanocellulose (NC) isolated from waste paper (newsprint and cardboard waste) were performed for the first time. It was established that the structure of the NC samples corresponds to the antiparallel model of cellulose Iβ. The degree of crystallinity of the samples determined by the modified Ruland method was ~64 %, which is lower than similar indicators of powder celluloses isolated from fibrous waste of plant celluloses, namely flax fiber and bleached hardwood cellulose. The largest size of the coherent scattering region (CSR) was observed along the fibril growth axis [001], indicating an elongated morphology of the crystallites. Using computer modeling, it was shown that the correspondence between the experimental and theoretical scattering curves is achieved by superposition of several types of clusters with different levels of ordering. Keywords: natural polymers, X-ray structural analysis, CSR, degree of crystallinity, computer modeling.
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