The reason for the revision of conjugated polymers Raman bands attribution
Prosanov I. Yu. 1, Sidelnikov A. A.1, Volodin V. A.2,3
1Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Rzhanov Institute of Semiconductor Physics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
3Novosibirsk State University, Novosibirsk, Russia

The bands similar to D and G-bands of carbonaceous materials and bands of conjugated polymers were observed in polyvinyl alcohol (PVA)-iodine complex Raman spectra. It contradicts to their common attribution because PVA has no C=C bonds. Based on this result it is supposed that treatment of sp2 hybridized carbon structures Raman behavior should be revised. Keywords: polyvinyl alcohol, PVA-iodine complex, hybrid interpolymeric complexes, conjugated polymers. DOI: 10.61011/EOS.2023.02.55795.3658-22
  1. Light Scattering in Solids III. Recent Results, ed. by M. Cardona, G. Guntherodt (Springer-Verlag. Berlin, Heidelberg, New York, 1982) Topics in Appl. Phys. 51, p. 3--57.
  2. H.M. Heise, R. Kuckuk, A.K. Ojha, V. Srivastava, B.P. Asthana. J. Raman Spectrosc., 40 (3), 344 (2008). DOI: 10.1002/jrs.2120
  3. Light Scattering in Solids VI. Recent Results, including high-Tc Superconductivity, ed. by M. Cardona, G. Guntherodt (Springer-Verlag, Berlin, Heidelberg, New York, 1991) Topics Appl. Phys., 68, p. 73--135
  4. V.V. Berdyugin, P.P. Shorygin, K.Ya. Burshtein, Yu.V. Korshak, M.A. Tienkopachev, A.V. Orlov. Russian Chemical Bulletin, 45 (8), 1912 (1996)
  5. N.M. Balzaretti, C.A. Perottoni, J.A. Herz da Jornada. J. Raman Spectrosc., 34, 259 (2003). DOI: 10.1002/jrs.999
  6. Micro- and Nano-photonic Materials and Devices, ed. by J.W. Perry, A. Scherer (Proceedings of SPIE, 2000) 3937, p. 132
  7. E. Mulazzi, A. Ripamonty, J. Very, B. Dulieu, E. Faulques, S. Lefrant. Synthetic Metals., 101, 196 (1999)
  8. B. Horovitz, Z. Vardeny, E. Ehrenfreund, O. Brafman. J. Phys. C: Solid State Phys., 19, 7291 (1986)
  9. J.-Y. Kim, S. Ando, A. S., Yu. Furukawa, M. Tasumi. Synthetic Metals, 89, 149 (1997)
  10. J. Tanaka, Ch. Tanaka. Synthetic Metals, 69, 647 (1995)
  11. G.A. Arbuckle, A.G. MacDiarmid, S. Lefrant, T. Verdon, E. Mulazzi, G.P. Brivio, X.Q. Yang, H.S. Woo, D.B. Tanner. Phys. Rev. B, 43 (6), 4739 (1991)
  12. J.-Y. Kim, Yu. Furukawa, A. Sakamoto, M. Tasumi. J. Phys. Chem. A, 106 (38), 8876 (2002). DOI: 10.1021/jp020948a
  13. I.Yu. Prosanov, A.A. Sidelnikov, S.A. Hanna. Semiconductors, 56 (3), 334 (2022). DOI: 10.21883/SC.2022.03.53119.9775A
  14. Chemistry and technology of water-soluble polymers, ed. by C.A. Finch (Springer Science + Business Media, New York, 1983), p. 287--306
  15. Y.-S. Choi, K. Miyasaka. J. Appl. Polymer Sci., 51, 613 (1994)
  16. Y.-S. Choi, Yu. Oishi, K. Miyasaka. Polymer Journal, 22, 601 (1990)
  17. T. Takahama, S.M. Saharin, K. Tashiro. Polymer, 99, 566 (2016). DOI: 10.1016/j.polymer.2016.07.055
  18. B. Orel, A.S. Vuk, R. Jese, P. Lianos, E. Stathatos, P. Judeinstein, P. Colomban. Solid State Ionics, 165, 235 (2003). DOI: 10.1016/j.ssi.2003.08.037
  19. A.Kh. Kuptsov, G.N. Zhizhin. Handbook of Fourier Transform Raman and Infrared Spectra of Polymers (Elsevier, Amsterdam, 1998)
  20. I.Yu. Prosanov, A.A. Matvienko. Phys. Sol. St., 52 (10), 2203 (2010). DOI: 10.1134/S1063783410100318
  21. S.J. Tans, A.R.M. Verschueren, C. Dekker. Nature, 393, 49 (1998). DOI: 10.1038/29954

Подсчитывается количество просмотров абстрактов ("html" на диаграммах) и полных версий статей ("pdf"). Просмотры с одинаковых IP-адресов засчитываются, если происходят с интервалом не менее 2-х часов.

Дата начала обработки статистических данных - 27 января 2016 г.


Ioffe Institute

Institute Officers:

Director: Sergei V. Ivanov

Contact us:

26 Polytekhnicheskaya, Saint Petersburg 194021, Russian Federation
Fax: +7 (812) 297 1017
Phone: +7 (812) 297 2245