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Selection of optimal frequencies near λ=4.5 μm for detecting nitrous oxide (N2O) absorption in the atmosphere
Russian version
Antotenko Y. V.1,2, Sherstov I. V.1,2
1Institute of Laser Physics, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk State Technical University, Novosibirsk, Russia
Email: antonen-ko.y@yandex.ru
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The absorption spectra of N2O, H2O vapor, CO, and CO2 isotopes were analyzed in the spectral range λ= 4-5 μm, where a strong absorption band ν3 of N2O centered at ~2225 cm-1 is located. To measure the absorption of N2O in a real atmosphere in the presence of absorption of interfering atmospheric gases (H2O vapor, CO, 12CO2, 13CO2), a number of N2O absorption lines near λ=4.5 μm (vibrational-rotational band ν3) and the corresponding radiation frequencies were selected, where the relative influence of the absorption of interfering atmospheric gases is minimal and amounts to no more than 2.2 %. For practical use, three optimal frequencies of rotational absorption lines in the ν3 N2O band near 4.5 μm are recommended, where the maximum sensitivity of N2O detection is achieved with a minimum relative influence of the absorption of interfering atmospheric gases: 2234.01 cm-1 (line R(12) N2O); 2234.75 cm-1 (line R(13) N2O); 2240.43 cm-1 (line R(21) N2O). In this case, the minimum relative influence of the absorption of interfering atmospheric gases (1.8 %) is observed on the R(21) absorption line of the ν3 N2O band. Keywords: laser gas analysis of the atmosphere, photoacoustic gas analyzer of N2O, detection of N2O absorption, absorption band ν3 of N2O.
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