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Photocatalytic properties of MgO-ZnO composites modified with Cu and Mn ions
Russian version
Gavrilova D. A. 1,2, Gavrilova M. A. 1, Evstropiev S. K. 1,2,3
1Saint-Petersburg State Institute of Technology (Technical University), St. Petersburg, Russia
2Vavilov State Optical Institute, St. Petersburg, Russia
3ITMO University, St. Petersburg, Russia
Email: amonobel@yandex.ru
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In this work, composites of the ZnO-MgO system modified with Cu and Mn ions were synthesized using the polymer sol-gel method. Their crystal structure, morphology, adsorption and photocatalytic properties, as well as the ability to photogenerate singlet oxygen were studied. The structure and properties of the materials were studied using X-ray diffraction, scanning electron microscopy and energy dispersive X-ray analysis, optical and luminescence spectroscopy. The obtained powder composites are characterized by a highly porous structure and consist of ZnO and MgO nanocrystals less than 20 nm in size. It was found that modifying ions Cu2+ and Mn2+ are introduced into the crystal lattices of ZnO and MgO during the synthesis and change their parameters. It was shown that ZnO-MgO composites modified with Cu and Mn ions have the ability to photogenerate chemically active singlet oxygen under the action of visible radiation (λ=405 nm). The composites demonstrate high rates of adsorption and photocatalytic decomposition of the Chicago Sky Blue diazo dye in aqueous solutions under the action of radiation with a wavelength of 395 nm. The dye adsorption kinetics is described by a pseudo-second-order kinetic equation. The composites demonstrate a high rate of photocatalytic dye degradation, described by a pseudo-first-order kinetic equation. Keywords: photocatalysis, MgO and ZnO nanocrystals, singlet oxygen.
  1. E.S. Araujo, M.F.G. Pereira, G.M.G. da Silva, G.F. Tavares, C.Y.B. Oliveira, P.M. Faia. Toxics, 11, 658 (2023). DOI: 10.3390/toxics11080658
  2. M.A. Gavrilova, D.A. Gavrilova, S.K. Evstropiev, A.A. Shelemanov, I.V. Bagrov. Ceramics, 6 (3), 1667--1681 (2023). DOI: 10.3390/ceramics6030103K
  3. E.A. Kozlova, V.N. Parmon. Uspekhi khimii, 86 (9), 870--906 (2017) (in Russian). DOI: 10.1070/RCR4739
  4. Samriti, R. Tyagi, O. Ruzimuradov, J. Prakash. Mater. Chem. Phys., 307, 128108 (2023). DOI: 10.1016/j.matchemphys.2023.128108
  5. N. Vela, M. Calin, M.J. Yanez-Gascon, I. Garrido, G. Perez-Lucas, J. Fenoll, S. Navarro. J. Photochem. Photobiol. A, 353, 271--278 (2018). DOI: 10.1016/j.jphotochemrev.2017.11.040
  6. C.S. Turchi, D.F. Ollis. J. Catal., 122 (1), 178--192 (1990). DOI: 10.1016/0021-9517(90)90269-P
  7. Y. Nosaka, A.Y. Nosaka. Chem. Rev., 117 (17), 11302--11336 (2017). DOI: 10.1021/acs.chemrev.7b00161
  8. T. Wang, H. Liu, X. Wang, L. Tang, J. Zhou, X. Song, L. Lv, W. Chen, Y. Chen, X. Li. ACS Catal., 13 (21), 13902--13911 (2023). DOI: 10.1021/acscatal.3c01478
  9. C. Zhang, X. Wang, J. Du, Z. Gu, Y. Zhao. Adv. Sci., 8 (3), 2002797 (2021). DOI: 10.1002/advs.202002797
  10. Y. Li, W. Zhang, J. Niu, Y. Chen. ACS Nano, 6, 5164--5173 (2012). DOI: 10.1021/nn300934k
  11. J. Ge, Y. Zhang, Y.-J. Heo, S.-J. Park. Catalysts., 9, 122 (2019). DOI: 10.3390/catal9020122
  12. D. Bulyga., S.K. Evstropiev. Opt. Spectrosc., 130 (9), 1188--1196 (2022). DOI: 10.21883/eos.2022.09.54839.3617-22
  13. B.M. Namoos, A.R. Mohamed, K.A. Ali. J. Solid State Chem., 320, 123834 (2023). DOI: 10.1016/j.jssc.2023.123834
  14. T. Wang, B. Tian, B. Han, D. Ma, M. Sun, A. Hanif, D. Xia, J. Shang. Energy \& Environ. Mater., 5, 711--730 (2022). DOI: 10.1002/eem2.12229
  15. Ranjbari, K. Demeestere, F. Verpoort, K.-H. Kim, P.M. Heynderick. Chem. Engin. J., 431 (4), 133349 (2022). DOI: 10.1016/j.cej.2021.133349
  16. F. Achouri, S. Corbel, L. Balan, K. Mozet, E. Girot, G. Medjahdi, M.B. Said, A. Ghrabi, R. Schneider. Mater. Design., 101, 309--316 (2016). DOI: 10.1016/j.matdes.2016.04.015
  17. S. Lamkhao, S. Tandorn, G. Rujijanagul, C. Randorn. Mater. Today Sust., 23, 100482 (2023). DOI: 10.1016/j.mtsust.2023.100482
  18. S.K. Evstropiev, A.V. Karavaeva, V.N. Vasilyev., N.V. Nikonorov, V.A. Aseev, K.V. Dukelskii, L.L. Lesnykh. J. Mater. Sci. Engin. B, 264, 114877 (2021). DOI: 10.1016/j.mseb.2020.114877
  19. S. Das, V.C. Srivastava. Nanotechnol. Rev., 7 (3), 267--282 (2018). DOI: 10.1515/ntrev-2017-0144
  20. J. Aliaga, N. Cifuentes, G. Gonzalez, C. Sotomayor-Torres, E. Benavente. Catalysts, 8, 374 (2018). DOI: 10.3390/catal8090374
  21. H. Lachheb, F. Ajala, A. Hamrouni, A. Houas, F. Parino, L. Palmisano. Catal. Sci. Technol., 7, 4041--4047 (2017). DOI: 10.1039/c7cy01085k
  22. A.A. Shelemanov, R.K. Nuryev, S.K. Evstropiev, V.M. Kiselev., N.V. Nikonorov. Opt. Spectrosc., 129 (12), 1300--1305 (2021). DOI: 10.1134/S0030400X21090198
  23. V. Etacheri, R. Roshant, V. Kumar. ACS Appl. Mater. Interfaces., 4 (5), 2717--2725 (2012). DOI: 10.1021/am300359h
  24. A. Hamrouni, N. Moussa, F. Parrino, A. Di Paola, A. Hous, L. Palmisano. J. Molec. Catal. A, 390, 133--141 (2014). DOI: 10.1016/j.molcata.2014.03.018
  25. R. Ebrahimi, K. Hosseinsadeh, A. Maleki, R. Ghanbari, R. Rezaee, M. Safari, B. Shahmoradi, H. Daraei, A. Jafari, K. Yetilmezsoy, S.H. Puttaiah. J. Environ. Health Sci. Engin., 17, 479--492 (2019). DOI: 10.1007/s40201-019-00366-x
  26. S. Evstropiev, A. Shelemanov, I. Bagrov, A. Karavaeva, K. Portnova, N. Nikonorov. Catal. Res., 4 (3) (2024). DOI: 10.21926/cr.2403008
  27. Vaishali Amrute, A. Monika, K.K. Supin, M. Vasundhara, Anupama Chanda. RSC Adv., 14, 32786--32801 (2024). DOI: 10.1039/d4ra05197a
  28. M.V. Gallegos, M.A. Peluso, H. Thomas, L.C. Damonte, J. Sambeth. J. Alloys Comp., 689, 416--424 (2016). DOI: 10.1016/j.jakkcom.2016.07.283
  29. Z. Gultekin, M. Alper, M.C. Haci ismailoglu, C. Akay. J. Mater. Sci.: Mater. Electron., 34, 438 (2023). DOI: 10.1007/s10854-023-09886-7
  30. K.V. Dukel'skii, S.K. Evstrop'ev. J. Optical Technology, 78 (2), 137--144 (2011). DOI: 10.1364/JOT.78.000137
  31. T. Daimon, Y. Nosaka. J. Phys. Chem. C, 111, 4420--4424 (2007). DOI: 10.1021/jp070028y
  32. M.B. Hillyer, J.H. Jourdan, S. Nam, M.W. Easson, B.D. Condon. Nanomater., 12, 1621 (2022). DOI: 10.3390/nano12101621
  33. I.A. Pronin, B.V. Donkova, D.Tz. Dimitrov, I.A. Averin, J.A. Pencheva, V.A. Moshnikov. Semiconductors, 48 (7) 842--847 (2014). DOI: 10.1134/s1063782614070173
  34. Z. Zainal, L.K. Hui, M.Z. Hussein, Y.H. Taufiq-Yap, A.H. Abdullah, I. Ramli. J. Hazard. Mater., 125, 113--120 (2005). DOI: 10.1016/j.jhazmat.2005.05.013
  35. H. Morkoc, U. Ozgur. Zinc Oxide: Fundamentals, Materials, and Device Technology (Wiley-VCH, Berlin, 2009). DOI: 10.1002/9783527623945
  36. R.D. Shannon. Acta Cryst., 32, 751--767 (1976). DOI: 10.1107/s0567739476001551
  37. Z. Ma, F. Ren, X. Ming, Y. Long, A.A. Volinsky. Materials, 12 (1), 196 (2019). DOI: 10.3390/ma12010196
  38. O. Bilgili. Acta Phys. Polonica A, 136 (3), 460--466 (2019). DOI: 10.12693/APhysPolA.136.460
  39. C.-Y. Tsay, M.-C. Wang, S.-C. Chiang. Mater. Trans., 49 (5), 1186--1191 (2008). DOI: 10.2320/matertrans.MER2007334
  40. L. Srinivasa Rao, T. Venkatappa Rao, Sd. Naheed, P. Venkateswara Rao. Mater. Chem. Phys., 203, 133--140 (2018). DOI: 10.1016/j.matchemphys.2017.09.048
  41. E.H. Kisi, M.M. Elcombe. Acta Cryst. Struct. Commun., 45 (12), 1867--1870 (1989). DOI: 10.1107/S0108270189004269
  42. R. Ullah, J. Dutta. J. Hazard. Mater., 156 (1-3), 194--200 (2008). DOI: 10.1016/j.jhazmat.2007.12.033
  43. S. Lagergren. Handlingar, 24, 1--39 (1898)
  44. C. Tian, H. Zhao, H. Sun, K. Xiao, P.K. Wong. Chem. Engin. J., 381, 122760 (2020). DOI: 10.1016/j.cej.2019.122760
  45. E.D. Revellame, D.L. Fortela, W. Sharp, R. Hernandez, M.E. Zappi. Clean. Engin. Technol., 1, 100032 (2020). DOI: 10.1016/j.clet.2020.100032
  46. S. Phromma, T. Wutikhun, P. Kasamechonchung, T. Eksangsri, C. Sapcharoenkun. Appl. Sci., 10, 993 (2020). DOI: 10.3390/app10030993

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