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Formation of ordered perovskite nanostructures by nanoimprinting
Russian version
Lebedev D.V.1,2,3, Kochetkov F.M.1,3, Yakubova A.A.1, Solomonov N.A.1,3, Kenesbay R.1, Minev D.V.1, Makarov S.V.4, Mukhin I.S.1,3
1Alferov Federal State Budgetary Institution of Higher Education and Science Saint Petersburg National Research Academic University of the Russian Academy of Sciences, St. Petersburg, Russia
2Institute for Analytical Instrumentation of the Russian Academy of Sciences, Saint Petersburg, Russia
3Peter the Great Saint-Petersburg Polytechnic University, St. Petersburg, Russia
4ITMO University, St. Petersburg, Russia
Email: Denis.v.lebedev@gmail.com
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A new versatile method for synthesis of ordered nanostructures from halide perovskite CsPbBr3 by nanoimprinting is proposed and implemented experimentally. The method allows one to form extensive (with an area up to 25 mm2) homogeneous regions containing two types of perovskite structures: ordered arrays of individual nanoparticles and microflakes with a nanostructured surface. A study of the optical properties of the synthesized samples by photoluminescence microspectroscopy revealed narrow resonance emission peaks at 523 nm for a particle array and at 525 nm for flakes (the width of the spectral line at half maximum was 19 and 21 nm, respectively). The intensity of photoluminescence, which is determined by the total volume of excited perovskite material, was significantly higher in the case of flakes. Keywords: nanostructures, perovskites, optical spectroscopy, synthesis technique.
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